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Surface Morphology Study of Nanostructured Lead-Free Solder Alloy Sn-Ag-Cu Developed by Electrodeposition: Effect of Current Density Investigation

机译:电沉积开发的纳米结构无铅锡合金Sn-Ag-Cu的表面形态研究:电流密度研究的影响

摘要

Nanostructured lead-free solder Sn-Ag-Cu (SAC) was developed by electrodeposition method at room temperature. Electrolite bath which comprised of the predetermined quantity of tin methane sulfonate, copper sulfate and silver sulfate were added sequentially to MSA solution. The methane sulphonic acid (MSA) based ternary Sn-Ag-Cu bath was developed by using tin methane sulfonate as a source of Sn ions while the Cu+ and Ag+ ions were obtained from their respective sulfate salts. The rate of the electrodeposition was controlled by variation of current density. The addition of the buffer, comprising of sodium and ammonium acetate helped in raising the pH solution. During the experimental procedure, the pH of solution, composition of the electrolite bath, and the electrodeposition time were kept constant. The electrodeposited rate, deposit composition and microstructure were investigated as the effect of current density. The electrodeposited solder alloy was characterized for their morphology using Field Emission Scanning Electron Microscope (FESEM). In conclusion, vary of current density will play significant role in the surface morphology of nanostructured lead-free solder SAC developed. Doi: 10.12777/ijse.5.2.51-55 [How to cite this article: Yusof, S.M., Hadi, A., and Jai, J. (2013). Surface Morphology Study of Nanostructured Lead-Free Solder Alloy Sn-Ag-Cu Developed by Electrodeposition: Effect of Current Density Investigation. International Journal of Science and Engineering, 5(2):51-55. Doi: 10.12777/ijse.5.2.51-55
机译:在室温下通过电沉积方法开发了纳米结构的无铅焊料Sn-Ag-Cu(SAC)。将由预定量的甲磺酸锡,硫酸铜和硫酸银组成的Electrolite浴依次添加到MSA溶液中。基于甲烷磺酸(MSA)的三元Sn-Ag-Cu镀液是通过使用甲磺酸锡作为Sn离子源而开发的,而Cu +和Ag +离子则是从它们各自的硫酸盐中获得的。电沉积的速率通过电流密度的变化来控制。加入由乙酸钠和乙酸铵组成的缓冲液有助于提高pH溶液。在实验过程中,溶液的pH,电石浴的组成和电沉积时间保持恒定。研究了电沉积速率,沉积物组成和微观结构对电流密度的影响。使用场发射扫描电子显微镜(FESEM)对电沉积焊料合金的形貌进行了表征。总之,电流密度的变化将在开发的纳米结构无铅焊料SAC的表面形态中起重要作用。 Doi:10.12777 / ijse.5.2.51-55 [如何引用本文:Yusof,S.M.,Hadi,A.和Jai,J.(2013)。电沉积开发的纳米结构无铅锡合金Sn-Ag-Cu的表面形貌研究:电流密度研究的影响。国际科学与工程杂志,5(2):51-55。 Doi:10.12777 / ijse.5.2.51-55

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